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Who was the first to discover out this siphon thing, And when?

It is tolerably certain that Ctesibius was the discoverer of the principle of the siphon. His student, Hero of Alexandria, wrote extensively about siphons in the treatise, Pneumatica. Even before the Greeks, Egyptian reliefs from 1500 B.C. depict siphons used to extract liquids from large storage jars.

Ctesibius or Ktesibios or Tesibius (Greek Κτησίβιος) (fl. 285–222 BC) was a Greek or Egyptian inventor and mathematician in Alexandria, Ptolemaic Egypt. He wrote the first treatises on the science of compressed air and its uses in pumps (and even a cannon). This, in combination with his work on the elasticity of air On pneumatics, earned him the title of "father of pneumatics." None of his written work has survived, including his Memorabilia, a compilation of his research that was cited by Athenaeus.